
When you handle charging with a power supply, you must set voltage and current precisely for each battery chemistry. The table below demonstrates how different lithium variants require unique charge voltages to optimize performance and safety.
Battery Chemistry Variant | Nominal Voltage (V) | Max Charge Voltage (V) |
---|---|---|
LCO Lithium battery | 3.6 | 4.2 |
NMC Lithium battery | 3.7 | 4.2 |
LMO Lithium battery | 3.7 | 4.2 |
LiFePO4 Lithium battery | 3.2 | 3.65 |

You improve battery safety and extend lifespan by monitoring temperature and voltage during charge. Manual control lets you adapt charging with a power supply to lithium, lead acid, NiCd, or NiMH batteries, but you must stay alert throughout the process.
Key Takeaways
Set voltage and current precisely for each battery type to ensure safe and efficient charging. Always check the battery datasheet for correct values.
Monitor temperature, voltage, and current closely during charging to prevent overcharge, overheating, and damage. Use a battery management system (BMS) for lithium batteries.
Charge batteries in a well-ventilated area and never leave them unattended. Follow safety standards and stop charging when current drops to about 3% of the rated value.
Part 1: Charging with a Power Supply

1.1 Lithium-Ion Charging
When you charge lithium-ion batteries, you must use precise control. Charging with a power supply requires you to set both voltage and current limits for each cell. For most lithium-ion chemistries, such as NMC Lithium battery, LCO Lithium battery, and LMO Lithium battery, you set the full charge voltage at 4.20V per cell. For LiFePO4 Lithium battery, you set the voltage at 3.65V per cell. Always check the battery’s datasheet for the correct voltage.
You should follow the constant current constant voltage method. Start by setting the current to a safe charge rate, usually between 0.5C and 1C. For example, if your battery has a 10Ah capacity, set the current to 5A–10A. As the battery charges, the voltage rises. When the voltage reaches the full charge threshold, the power supply switches to constant voltage mode. The current will taper down. You should stop charging when the current drops to about 3% of the rated current. This ensures the battery is fully charged without overcharging.
⚠️ Tip: Never let any cell exceed its maximum voltage. Overcharging lithium-ion batteries can cause thermal runaway, fire, or explosion. Use a battery management system (BMS) for cell balancing and protection.
You must monitor temperature, voltage, and current throughout the process. Charging lithium-ion batteries at sub-freezing temperatures can cause permanent damage. Most lithium-ion batteries have built-in safety features, such as PTC devices, CIDs, and vents, but you should never rely solely on these. The documented failure rate for lithium-ion batteries is about one in 200,000, often due to internal defects. Always use high-quality, branded cells for critical applications in medical, robotics, security, infrastructure, and consumer electronics.
Step | Action | Details |
---|---|---|
1 | Set voltage | 4.20V/cell (NMC, LCO, LMO), 3.65V/cell (LiFePO4) |
2 | Set current | 0.5C–1C (based on battery capacity) |
3 | Monitor | Voltage, current, temperature |
4 | Terminate charge | When current drops to 3% of rated value |
5 | Safety | Never exceed voltage, use BMS, avoid sub-freezing temps |
You should avoid leaving lithium-ion batteries unattended during charging. Always use a well-ventilated area and follow industry standards such as IEC 61851, UL, and ISO 26262 for safety.
1.2 Lead Acid Charging
Charging with a power supply gives you flexibility when working with lead-acid batteries. You must calculate the charge voltage based on the number of cells. For a typical 12V battery (6 cells), set the voltage to 14.40V (2.40V per cell). Select a charge current between 10% and 30% of the battery’s rated capacity. For a 100Ah battery, set the current between 10A and 30A.
You should use the constant current constant voltage method. Begin with constant current until the battery voltage reaches the set point. The power supply then switches to constant voltage, and the current tapers down. You should terminate the charge when the current drops to about 3% of the rated capacity or after 16–24 hours if the current stabilizes at a low level. For maintenance, you can apply a float charge at about 2.25V per cell.
🔍 Note: Lead-acid batteries benefit from equalizing charges. Occasionally, you can increase the voltage by 10% above the recommended value for a short period to balance cells and reverse sulfation. Monitor temperature closely during this process.
Temperature control is critical. Every 8°C rise halves the battery’s lifespan. Always charge in a well-ventilated area to prevent gas buildup. Sealed lead-acid batteries, such as AGM and VRLA, require careful voltage control to avoid gassing and water loss.
Battery Type | Step-by-Step Charging Procedure | Key Performance Metrics |
---|---|---|
Lead Acid | 1. Calculate charge voltage by number of cells (e.g., 2.40V per cell). 2. Set power supply voltage accordingly (e.g., 14.40V for 6 cells). 3. Select charge current between 10% and 30% of rated capacity (C-rate). 4. Monitor temperature, voltage, and current during charging. 5. Terminate charge when current drops to ~3% of rated capacity or after 16–24 hours if current bottoms out. 6. Optional float charge at ~2.25V/cell. 7. Equalizing charge by increasing voltage 10% above recommended, with careful timing. | Voltage per cell: 2.40V (full charge), Float voltage: ~2.25V/cell, Charge current: 10–30% of rated capacity, Charge termination: current taper to 3% or time limit 16–24h |
You must follow safety standards such as UN ECE Regulation No. 100 and UL standards. These require insulation resistance above 1 megohm and protection against fire, explosion, and electrolyte leakage.
1.3 NiCd and NiMH Charging
Charging nickel-cadmium and charging nickel-metal-hydride batteries requires a different approach. You cannot rely on voltage alone to detect full charge. Instead, you should use temperature monitoring, negative delta V (NDV) detection, or timers.
For fast charging, set the current to 1C. For example, a 2Ah battery should be charged at 2A. The voltage per cell should not exceed 1.5V at 0.1C or 1.56V at 1C. As the battery approaches full charge, the voltage peaks and then drops slightly (NDV). For NiMH, the NDV signal is faint, so you should also monitor temperature. A lukewarm battery usually indicates it is fully charged.
💡 Tip: For trickle charging, set the current to 0.05C for NiMH and 0.1C for NiCd. This maintains the battery without overcharging.
You should use a timer if you charge at low rates, as NDV detection becomes unreliable. Remove the batteries when they are fully charged to prevent overcharge. NiMH batteries are more sensitive to overcharge than NiCd. Aggressive charging can increase capacity by about 6% but may reduce cycle life.
Aspect | Details |
---|---|
Charge Detection Methods | Negative Delta V (NDV), voltage thresholds, temperature monitoring, timers; NDV detects ~5mV per cell drop |
Typical Charging Currents | Fast charge at 1C (step-differential method), trickle charge: 0.05C for NiMH, 0.1C for NiCd |
Voltage Settings | Max ~1.5V per cell at 0.1C, up to 1.56V at 1C charge current |
Charging Techniques | Step-differential charge: initial fast charge, rest periods, current reductions until full charge |
Overcharge Risks | NiMH sensitive to overcharge; trickle charge set low to avoid damage; NiCd more tolerant |
Practical Advice | Monitor temperature (lukewarm indicates full charge), estimate charge time, remove batteries when full |
You must always charge nickel-based batteries in a well-ventilated area. Never leave batteries unattended during charging. Follow UL and IEC standards for safety.
📋 Industry Standards:
ISO 26262, UN ECE Regulation No. 100, IEC 61851, UL, and SAE standards set benchmarks for insulation resistance, overcharge protection, and mechanical safety.
These standards help you ensure safe charging with a power supply for all battery chemistries.
If you need custom battery solutions for industrial, medical, robotics, or infrastructure projects, you can consult our experts for tailored advice.
Part 2: Charging Different Types of Batteries – Key Considerations

2.1 Voltage and Current Settings
You must set voltage and current precisely for each battery chemistry to ensure safe and efficient charging. For lithium batteries, such as NMC Lithium battery, LCO Lithium battery, LMO Lithium battery, and LiFePO4 Lithium battery, the recommended voltage range and C-rate depend on the chemistry and application. The table below summarizes typical parameters:
Chemistry | Voltage Range (V) | Nominal Capacity (Ah) | Charging C-rate | Full Charge Voltage (V/cell) |
---|---|---|---|---|
NMC | 2.7–4.2 | 0.74 | 1 | 4.20 |
LCO | 3.2–4.2 | 2.1 | 1 | 4.20 |
LMO | 3.0–4.2 | 1.5 | 1 | 4.20 |
LiFePO4 | 2.0–3.65 | 1.1 | 1–8 | 3.65 |
You should always check the battery datasheet for the correct full charge voltage and recommended current. For lead acid batteries, set the charge voltage at 2.40V per cell and select a current between 10% and 30% of rated capacity. For NiCd and NiMH batteries, use a charge current of 1C for fast charging and monitor for full charge using temperature or negative delta V.
⚡ Tip: Statistical analysis of voltage and current curves, such as mean and entropy, helps you track battery health and optimize charging protocols. Incremental capacity analysis (ICA) can reveal degradation patterns and support predictive maintenance.
2.2 Monitoring and Safety
You must monitor batteries closely during charging to prevent overcharge, overheating, or cell imbalance. Use temperature sensors to detect abnormal rises, especially with lithium batteries. For lithium battery packs, a battery management system is essential for cell balancing and protection.
Always charge batteries in a well-ventilated area and never leave them unattended. Use protection equipment such as fuses and thermal cutoffs. For lithium batteries, avoid charging below 0°C or above 45°C. For lead acid batteries, monitor for gas buildup. For nickel-based batteries, use timers or temperature cutoffs to terminate charge at full charge.
Quick-Reference Checklist for Safe Manual Charging
Set voltage and current according to battery chemistry and datasheet.
Monitor temperature, voltage, and current throughout charging.
Use a BMS for lithium battery packs.
Terminate charge at full charge voltage and when current drops to 3% of rated value.
Charge batteries in a safe, ventilated environment.
Apply equalization or balancing as needed.
You must understand the unique requirements of different batteries before you charge them. Manual charging brings risks, especially for lithium battery packs. Continuous monitoring and safety equipment help prevent failures. A maritime case study shows that tracking state of health for batteries can avoid hazardous incidents. Always use the quick-reference checklist and consult manufacturer guidelines. For custom battery solutions, contact our experts.
FAQ
1. How do you safely charge a lithium battery pack with a power supply?
You set voltage and current limits based on the battery’s datasheet. Always monitor temperature and use a BMS for cell balancing and protection.
2. What is the main risk when charging NMC Lithium battery packs manually?
Overcharging or exceeding voltage limits can cause thermal runaway. You must use precise voltage control and monitor each cell during the process.
3. Where can you get custom lithium battery solutions for industrial projects?
You can contact Large Power for expert consultation and tailored lithium battery pack solutions for your business needs.